A Coordination Polymer With a (3,4)-Connected (6<sup>2</sup>.8)<sub>2</sub>(6<sup>2</sup>.8<sup>4</sup>) 3D Network: Synthesis, Crystal Structure and Luminescent Properties

  • Guang-Xiang Liu
    a School of Biochemical and Environment Engineering , Nanjing Xiaozhuang University , Nanjing , P. R. China
  • Wei Guo
    a School of Biochemical and Environment Engineering , Nanjing Xiaozhuang University , Nanjing , P. R. China
  • Sadafumi Nishihara
    b Department of Physical Science, Graduate School of Science , Osaka Prefecture University , Sakai , Osaka , Japan
  • Xiao-Ming Ren
    c Department of Applied Chemistry, College of Science , Nanjing University of Technology , Nanjing , P. R. China

書誌事項

公開日
2012-10-01
資源種別
journal article
DOI
  • 10.1080/15533174.2012.680092
公開者
Informa UK Limited

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説明

The 3D Cd(II) coordination polymer Cd2(ODPA)(bpe)(py) (H2O)2 (1) with 3,3′,4,4′-oxydiphthalic acid (H4ODPA) and 1,2-bis(4-pyridyl)ethane (bpe) was synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectrum, and single-crystal X-ray diffraction techniques. X-ray crystallographic studies of 1 reveal that this metal-organic complex has an interesting (3,4)-connected 3D network with binary nodes. The Cd atoms are three-connected nodes and the ODPA ligands are four-connected nodes. Luminescent study indicates 1 has an emissive maximum at 408 nm in the solid state at room temperature.

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