Structural Requirements for Surface-Induced Aromatic Stabilization

DOI Web Site 被引用文献2件 参考文献23件 オープンアクセス

書誌事項

公開日
2014
資源種別
journal article
権利情報
  • https://www.cambridge.org/core/terms
DOI
  • 10.1557/opl.2014.348
公開者
Springer Science and Business Media LLC

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説明

<jats:title>ABSTRACT</jats:title><jats:p>Surface-induced aromatic stabilization (SIAS), a recently proposed mechanism leading to a formation of charge-transfer (CT) states at organic/metal (O/M) interfaces [G. Heimel, <jats:italic>et al.</jats:italic>, <jats:italic>Nat. Chem.</jats:italic><jats:bold>5</jats:bold>, 187 (2013)], was investigated for an aromatic hydrocarbon, diindenoperylene (DIP), by means of synchrotron radiation-based ultraviolet photoelectron spectroscopy (UPS). By employing DIP and noble metal substrates (Ag and Cu), we confirmed the formation of CT states, indicating that an inclusion of a specific functional group with a hetero-atom within adsorbate molecules as suggested before is not necessarily required for the formation of CT states mediated by the SIAS. With a comparison of the mother and analogue molecules, perylene and PTCDA, we discuss the structural requirement for the realization of the SIAS.</jats:p>

収録刊行物

  • MRS Proceedings

    MRS Proceedings 1647 mrsf13-1647-gg01-03-, 2014

    Springer Science and Business Media LLC

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