Half-Titanocenes Containing Anionic Ancillary Donor Ligands: Effective Catalyst Precursors for Ethylene/Styrene Copolymerization

DOI Web Site 参考文献86件 オープンアクセス
  • Kotohiro Nomura
    Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami Osawa, Hachioji, Tokyo 192-0397, Japan

書誌事項

公開日
2013-02-18
資源種別
journal article
権利情報
  • https://creativecommons.org/licenses/by/3.0/
DOI
  • 10.3390/catal3010157
公開者
MDPI AG

説明

<jats:p>This review summarizes recent results for ethylene/styrene copolymerization using half-titanocenes containing anionic donor ligands, Cp’TiX2(Y) (X = halogen, alkyl; Y = aryloxo, ketimide etc.)–cocatalyst systems. The product composition, the styrene incorporation and microstructures in the resultant copolymers are highly influenced by the anionic donor employed. A methodology for an exclusive synthesis of the copolymers even under high temperature and high styrene concentrations has been introduced on the basis of a proposed catalytically-active species in this catalysis.</jats:p>

収録刊行物

  • Catalysts

    Catalysts 3 (1), 157-175, 2013-02-18

    MDPI AG

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