In Situ Spectroscopic Analysis of the Carbothermal Reduction Process of Iron Oxides during Microwave Irradiation

  • Jun Fukushima
    Department of Applied Chemistry, Tohoku University, Aoba Aramaki, Sendai, Miyagi 980-8579, Japan
  • Hirotsugu Takizawa
    Department of Applied Chemistry, Tohoku University, Aoba Aramaki, Sendai, Miyagi 980-8579, Japan

書誌事項

公開日
2018-01-11
資源種別
journal article
権利情報
  • https://creativecommons.org/licenses/by/4.0/
DOI
  • 10.3390/met8010049
公開者
MDPI AG

説明

<jats:p>The effects of microwave plasma induction and reduction on the promotion of the carbothermal reduction of iron oxides (α-Fe2O3, γ-Fe2O3, and Fe3O4) are investigated using in situ emission spectroscopy measurements during 2.45 GHz microwave processing, and the plasma discharge (such as CN and N2) is measured during microwave E-field irradiation. It is shown that CN gas or excited CN molecules contribute to the iron oxide reduction reactions, as well as to the thermal reduction. On the other hand, no plasma is generated during microwave H-field irradiation, resulting in thermal reduction. Magnetite strongly interacts with the microwave H-field, and the reduction reaction is clearly promoted by microwave H-field irradiation, as well as thermal reduction reaction.</jats:p>

収録刊行物

  • Metals

    Metals 8 (1), 49-, 2018-01-11

    MDPI AG

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