Synthesis of Cis-Cisoid or Cis-Transoid Poly(Phenyl-Acetylene)s Having One or Two Carbamate Groups as Oxygen Permeation Membrane Materials
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- Yu Zang
- Key laboratory of polymer matrix composites, Heilongjiang Province, College of Materials Science and Engineering, Qiqihar University, Wenhua Street 42, Qiqihar, Heilongjiang 161006, China
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- Yinghui Lun
- Department of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang, Hunan 421002, China
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- Masahiro Teraguchi
- Chemistry and Chemical Engineering, Graduate School of Science and Technology, Niigata University, Ikarashi 2-8050, Nishi-ku, Niigata 950-2181, Japan
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- Takashi Kaneko
- Chemistry and Chemical Engineering, Graduate School of Science and Technology, Niigata University, Ikarashi 2-8050, Nishi-ku, Niigata 950-2181, Japan
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- Hongge Jia
- Key laboratory of polymer matrix composites, Heilongjiang Province, College of Materials Science and Engineering, Qiqihar University, Wenhua Street 42, Qiqihar, Heilongjiang 161006, China
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- Fengjuan Miao
- College of Communications and Electronics Engineering, Qiqihar University, Wenhua Street 42, Qiqihar, Heilongjiang 161006, China
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- Xunhai Zhang
- Key laboratory of polymer matrix composites, Heilongjiang Province, College of Materials Science and Engineering, Qiqihar University, Wenhua Street 42, Qiqihar, Heilongjiang 161006, China
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- Toshiki Aoki
- Key laboratory of polymer matrix composites, Heilongjiang Province, College of Materials Science and Engineering, Qiqihar University, Wenhua Street 42, Qiqihar, Heilongjiang 161006, China
説明
<jats:p>Three new phenylacetylene monomers having one or two carbamate groups were synthesized and polymerized by using (Rh(norbornadiene)Cl)2 as an initiator. The resulting polymers had very high average molecular weights (Mw) of 1.4–4.8 × 106, with different solubility and membrane-forming abilities. The polymer having two carbamate groups and no hydroxy groups in the monomer unit showed the best solubility and membrane-forming ability among the three polymers. In addition, the oxygen permeability coefficient of the membrane was more than 135 times higher than that of a polymer having no carbamate groups and two hydroxy groups in the monomer unit with maintaining similar oxygen permselectivity. A better performance in membrane-forming ability and oxygen permeability may be caused by a more extended and flexible cis-transoid conformation and lower polarity. On the other hand, the other two new polymers having one carbamate group and two hydroxy groups in the monomer unit showed lower performances in membrane-forming abilities and oxygen permeabilities. It may be caused by a very tight cis-cisoid conformation, which was maintained by intramolecular hydrogen bonds.</jats:p>
収録刊行物
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- Membranes
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Membranes 10 (9), 199-, 2020-08-25
MDPI AG
