Synthesis of Peripherally Arylated Tetrathiafulvalenes Extended with an Anthraquinoid Spacer via Pd-Catalyzed C–H Arylation and Construction of a Double-Helical Cobalt-Based Metal-Organic Framework
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- Yohji Misaki
- Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
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- Aya Yoshimura
- Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
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- Keisuke Henmi
- Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
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- Hitoshi Kimura
- Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
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- Ryo Sakakibara
- Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
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- Rika Ochi
- Faculty of Science and Technology, Kochi University
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- Takashi Shirahata
- Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
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- Hideki Yorimitsu
- Department of Chemistry, Graduate School of Science, Kyoto University
説明
<jats:p>Peripherally arylated tetrathiafulvalenes with an anthraquinoid spacer (TTFAQs) have been synthesized by using palladium-catalyzed direct C–H arylation of the 1,3-dithiole rings. Electrochemical analysis by cyclic voltammetry has revealed that the new tetraarylated TTFAQs show one pair of simultaneous two-electron transfer waves as the parent TTFAQ does. The hydrolysis of the tetra(p-ethoxycarbonylphenyl)-substituted derivative affords the corresponding tetracarboxylic acid, which forms a new double-helical metal-organic framework upon complexation with cobalt(III) nitrate.</jats:p>
収録刊行物
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- Synthesis
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Synthesis 53 (02), 326-331, 2020-07-13
Georg Thieme Verlag KG
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詳細情報 詳細情報について
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- CRID
- 1360009142861467392
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- ISSN
- 1437210X
- 00397881
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- 資料種別
- journal article
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- データソース種別
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- Crossref
- KAKEN
- OpenAIRE
