Ribosomal synthesis of dehydrobutyrine- and methyllanthionine-containing peptides

DOI Web Site PubMed 被引用文献26件

書誌事項

公開日
2009
DOI
  • 10.1039/b904314d
公開者
Royal Society of Chemistry (RSC)

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説明

We report here the ribosomal synthesis of methyllanthionine-containing cyclic peptides involving a site-specific incorporation of vinylglycine under the reprogrammed genetic code, followed by the isomerization of the vinylglycine to dehydrobutyrine, and the subsequent intramolecular Michael addition of a cysteine residue placed at a downstream position of the vinylglycine.

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