A Polydiacetylene From an Asymmetrically-Substituted Octatetrayne Compound for Nonlinear Optics

DOI Web Site 被引用文献3件
  • Shujiokada Takanori Doi
    b Toda Kogyo Corp. , 1-4 Meijishinkai, Otake , Hiroshima , 739-06 , Japan
  • Naoto Kikuchi
    c National Institute of Materials and Chemical Research , 1-1 Higashi, Tsukuba, Ibaraki , 305 , Japan
  • Kikuko Hayamizu
    c National Institute of Materials and Chemical Research , 1-1 Higashi, Tsukuba, Ibaraki , 305 , Japan
  • Hiro Matsuda
    c National Institute of Materials and Chemical Research , 1-1 Higashi, Tsukuba, Ibaraki , 305 , Japan
  • Hachiro Nakanishi
    a Institute for Chemical Reaction Science, Tohoku University , 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi , 980 , Japan

書誌事項

公開日
1994-06
DOI
  • 10.1080/10587259408039195
公開者
Informa UK Limited

この論文をさがす

説明

Abstract Since solid-state polymerization reaction of symmetrically-substituted octatetrayne derivatives can start from both 1,4- and 5,8-positions in the same column of the monomers in crystals, deterioration of crystallinity seemed to occur to some extent in the course of polymerization. Thus, an asymmetrically-substituted octatetrayne, i.e. 13-(4-butyl-2,3,5,6-tetrafluorophenyl)-6,8,10,12-tridecatetraynyl N-(butoxycarbonylmethyl)-carbamate (5BCMU-4A-BTFP), was synthesized and its polymerization site was examined using high resolution solid-state 13CNMR spectroscopy. And it was shown that asymmetrical substitution of octatetrayne is effective for site-selective 1,4-addition polymerization. Absorption spectrum and third-order nonlinear optical properties of the 5BCMU-4A-BTFP polymer were also investigated.

収録刊行物

被引用文献 (3)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ