Magnetic anisotropy and coercivity of Fe3Se4 nanostructures

  • Gen Long
    University at Buffalo, the State University of New York 1 , Buffalo, New York 14260, USA
  • Hongwang Zhang
    University at Buffalo, the State University of New York 1 , Buffalo, New York 14260, USA
  • Da Li
    University at Buffalo, the State University of New York 1 , Buffalo, New York 14260, USA
  • Renat Sabirianov
    University of Nebraska-Omaha 3 , Omaha, Nebraska 68182, USA
  • Zhidong Zhang
    Shenyang National Laboratory for Materials Science, Institute of Metal Research and International Center for Materials Physics, Chinese Academy of Sciences 2 , Shenyang, Liaoning 110016, China
  • Hao Zeng
    University at Buffalo, the State University of New York 1 , Buffalo, New York 14260, USA

書誌事項

公開日
2011-11-14
DOI
  • 10.1063/1.3662388
公開者
AIP Publishing

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説明

<jats:p>The hard magnetic properties of Fe3Se4 nanostructures were studied both experimentally and theoretically. Magnetic measurements showed that Fe3Se4 nanoparticles can exhibit giant coercivity exceeding 40 kOe at low temperature (10 K). This unusually large coercivity is attributed to the uniaxial magnetocrystalline anisotropy of the monoclinic structure of Fe3Se4 with ordered cation vacancies. The measured anisotropy constant is 1.0 × 107 erg/cm3, consistent with the result from first-principles calculations. The magnetization reversal mechanism of the nanoparticles is found to be incoherent spin rotation.</jats:p>

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