Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(κ<sup>3</sup>-tmps)(CO)<sub>2</sub>NbE–R] (E = Si, Ge, Sn; tmps = MeSi(CH<sub>2</sub>PMe<sub>2</sub>)<sub>3</sub>; R = aryl)
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- Alexander C. Filippou
- Institut für Anorganische Chemie
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- David Hoffmann
- Institut für Anorganische Chemie
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- Gregor Schnakenburg
- Institut für Anorganische Chemie
説明
<p>A systematic, efficient route to the first heavier tetrylidyne complexes of niobium [(κ3-tmps)(CO)2NbE–R] (E = Si–Sn; R = aryl) starting from the carbonyl niobate (NMe4)[Nb(CO)4(κ2-tmps)] is presented.</p>
収録刊行物
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- Chemical Science
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Chemical Science 8 (9), 6290-6299, 2017
Royal Society of Chemistry (RSC)
