Covalent Organic Frameworks for CO<sub>2</sub> Capture

  • Yongfei Zeng
    Division of Chemistry and Biological Chemistry School of Physical & Mathematical Sciences Nanyang Technological University 21 Nanyang Link 637371 Singapore
  • Ruqiang Zou
    Singapore Peking University Research Centre for a Sustainable Low‐Carbon Future 1 Create Way 138602 Singapore
  • Yanli Zhao
    Division of Chemistry and Biological Chemistry School of Physical & Mathematical Sciences Nanyang Technological University 21 Nanyang Link 637371 Singapore

書誌事項

公開日
2016-02-29
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/adma.201505004
公開者
Wiley

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説明

<jats:p>As an emerging class of porous crystalline materials, covalent organic frameworks (COFs) are excellent candidates for various applications. In particular, they can serve as ideal platforms for capturing CO<jats:sub>2</jats:sub> to mitigate the dilemma caused by the greenhouse effect. Recent research achievements using COFs for CO<jats:sub>2</jats:sub> capture are highlighted. A background overview is provided, consisting of a brief statement on the current CO<jats:sub>2</jats:sub> issue, a summary of representative materials utilized for CO<jats:sub>2</jats:sub> capture, and an introduction to COFs. Research progresses on: i) experimental CO<jats:sub>2</jats:sub> capture using different COFs synthesized based on different covalent bond formations, and ii) computational simulation results of such porous materials on CO<jats:sub>2</jats:sub> capture are summarized. Based on these experimental and theoretical studies, careful analyses and discussions in terms of the COF stability, low‐ and high‐pressure CO<jats:sub>2</jats:sub> uptake, CO<jats:sub>2</jats:sub> selectivity, breakthrough performance, and CO<jats:sub>2</jats:sub> capture conditions are provided. Finally, a perspective and conclusion section of COFs for CO<jats:sub>2</jats:sub> capture is presented. Recent advancements in the field are highlighted and the strategies and principals involved are discussed.</jats:p>

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