New π -Donor Molecules with a Pyrazino Group and their Conducting Salts

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  • G. C. Papavassiliou
    Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48, Vassileos Constantinou Ave, Athens 116/35, Greece
  • Yohji Misaki
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 606-01, Japan
  • Kazuko Takahashi
    Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-77, Japan
  • Jun-ichi Yamada
    Department of Material Science, Faculty of Science, Himeji Institute of Technology, 1475-2 Kanaji, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan
  • G. A. Mousdis
    Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48, Vassileos Constantinou Ave, Athens 116/35, Greece
  • Takashi Sharahata
    Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-77, Japan
  • Toshihiro Ise
    Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-77, Japan

説明

<jats:title>Abstract</jats:title> <jats:p> The preparation and characterization of some π-donors with a pyrazine-edge-group as well as with tetrathiapentalene-, thiophene-, and dihydrobenzoselenophene-spacer-groups are de­ scribed. Some of these donors give conducting charge transfer complexes with TCNQ and/or cation radical salts with I<jats:sub>3</jats:sub> <jats:sup>-</jats:sup>, BF<jats:sub>4</jats:sub> <jats:sup>-</jats:sup>and PF<jats:sub>6</jats:sub> <jats:sup>-</jats:sup>as counter anions. </jats:p>

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