Controlled Trifluoromethylation Reactions of Alkynes through Visible‐Light Photoredox Catalysis
書誌事項
- 公開日
- 2013-11-20
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/anie.201308735
- 公開者
- Wiley
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説明
<jats:title>Abstract</jats:title><jats:p>The control of a reaction that can form multiple products is a highly attractive and challenging concept in synthetic chemistry. A set of valuable CF<jats:sub>3</jats:sub>‐containing molecules, namely trifluoromethylated alkenyl iodides, alkenes, and alkynes, were selectively generated from alkynes and CF<jats:sub>3</jats:sub>I by environmentally benign and efficient visible‐light photoredox catalysis. Subtle differences in the combination of catalyst, base, and solvent enabled the control of reactivity and selectivity for the reaction between an alkyne and CF<jats:sub>3</jats:sub>I.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 53 (2), 539-542, 2013-11-20
Wiley