Short-range order and concentration fluctuations in binary molten alloys

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<jats:p> The quasi-chemical theory and the quasi-lattice theory are discussed with a view to obtaining information about concentration fluctuations, S<jats:sub>CC</jats:sub>(0), and the short-range order parameter, α<jats:sub>1</jats:sub>, for regular and compound-forming molten alloys. The influence of the coordination number z and the interchange energy ω on the mixing properties of the alloy is critically examined. S<jats:sub>CC</jats:sub>(0) and α<jats:sub>1</jats:sub> have been found to be very useful in extracting microscopic information, like local ordering and segregation in molten systems. The problem of glass formation in compound-forming binary molten alloys is also briefly discussed. </jats:p>

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