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The Asymmetric Rotor II. Calculation of Dipole Intensities and Line Classification
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- Paul C. Cross
- Brown University, Providence, Rhode Island
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- R. M. Hainer
- Brown University, Providence, Rhode Island
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- Gilbert W. King
- Arthur D. Little, Inc., Cambridge, Massachusetts
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Description
<jats:p>A table of line strengths for rigid asymmetric rotors is given, by means of which to this approximation the relative intensities of all important rotational lines up to J < 13 for all bands of any molecule can be readily calculated, provided the asymmetry is roughly the same in the initial and final states. A classification of the irregularly spaced lines of the asymmetric rotor is made into ``sub-branches'' defined by the changes of the K values of the initial level in the limiting prolate and oblate symmetric rotors, and into ``wings'' which collect together lines of the sub-branches which have uniformly varying strength and Boltzmann factor, and fairly uniform spacing.</jats:p>
Journal
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- The Journal of Chemical Physics
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The Journal of Chemical Physics 12 (6), 210-243, 1944-06-01
AIP Publishing
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Details 詳細情報について
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- CRID
- 1360011146416063360
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- ISSN
- 10897690
- 00219606
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- Data Source
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- Crossref