Asymmetric synthesis of <i>trans-p</i>-menth-3-ene-1,2,8-triol, the monoterpene isolated from herbal plants
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- Shunsuke Konishi
- Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
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- Yusuke Ogura
- Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
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- Hirosato Takikawa
- Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
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- Hidenori Watanabe
- Department of Applied Biological Chemistry, Graduate School of Agricultural and Life Sciences, The University of Tokyo, Tokyo, Japan
Description
<jats:title>ABSTRACT</jats:title> <jats:p>The monoterpene, trans-p-menth-3-ene-1,2,8-triol, is a naturally occurring alcohol isolated from several herbal plants. In the present work, the asymmetric synthesis of both enantiomers of this natural product was achieved using Sharpless asymmetric dihydroxylation as the key step. A reversal of enantiofacial selectivity was observed in the asymmetric dihydroxylation.</jats:p>
Journal
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- Bioscience, Biotechnology, and Biochemistry
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Bioscience, Biotechnology, and Biochemistry 84 (1), 37-42, 2020-01-02
Informa UK Limited
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Keywords
Details 詳細情報について
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- CRID
- 1360013172701917440
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- ISSN
- 13476947
- 09168451
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- Data Source
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- Crossref