Covalent–Organic Frameworks: Advanced Organic Electrode Materials for Rechargeable Batteries

  • Tao Sun
    School of Materials Science and Engineering Nanyang Technological University Singapore 639798 Singapore
  • Jian Xie
    School of Materials Science and Engineering Nanyang Technological University Singapore 639798 Singapore
  • Wei Guo
    College of Chemistry Zhengzhou University Zhengzhou 450001 P. R. China
  • Dong‐Sheng Li
    College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Yichang Hubei 443002 P. R. China
  • Qichun Zhang
    School of Materials Science and Engineering Nanyang Technological University Singapore 639798 Singapore

説明

<jats:title>Abstract</jats:title><jats:p>Covalent–organic frameworks (COFs), featuring structural diversity, framework tunability and functional versatility, have emerged as promising organic electrode materials for rechargeable batteries and garnered tremendous attention in recent years. The adjustable pore configuration, coupled with the functionalization of frameworks through pre‐ and post‐synthesis strategies, enables a precise customization of COFs, which provides a novel perspective to deepen the understanding of the fundamental problems of organic electrode materials. In this review, a summary of the recent research into COFs electrode materials for rechargeable batteries including lithium‐ion batteries, sodium‐ion batteries, potassium‐ion batteries, and aqueous zinc batteries is provided. In addition, this review will also cover the working principles, advantages and challenges, strategies to improve electrochemical performance, and applications of COFs in rechargeable batteries.</jats:p>

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