Isotropic Anhydrous Superprotonic Conductivity Cooperated with Installed Imidazolium Molecular Motions in a 3D Hydrogen‐Bonded Phosphate Network
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- Shun Dekura
- The Institute for Solid State Physics The University of Tokyo Kashiwanoha 5-1-5 Kashiwa, Chiba 277-8581 Japan
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- Motohiro Mizuno
- Graduate School of Natural Science and Technology Kanazawa University Kakuma-machi, Kanazawa Ishikawa 920–1192 Japan
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- Hatsumi Mori
- The Institute for Solid State Physics The University of Tokyo Kashiwanoha 5-1-5 Kashiwa, Chiba 277-8581 Japan
書誌事項
- 公開日
- 2022-11-10
- 資源種別
- journal article
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/anie.202212872
- 10.1002/ange.202212872
- 公開者
- Wiley
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説明
<jats:title>Abstract</jats:title><jats:p>Utilizing molecular motion is essential for the use of anhydrous superprotonic molecular proton conductors (σ beyond 10<jats:sup>−4</jats:sup> S cm<jats:sup>−1</jats:sup>) as electrolytes in hydrogen fuel cells. However, molecular motion contributing to the improvement of intrinsic proton conduction has been limited and little clarified in relation to the proton conduction mechanism, limiting the development of material design guidelines. Here, a salt with a three‐dimensional (3D) hydrogen‐bonded (H‐bonded) phosphate network with imidazolium cations installed inside was studied, whose components are known to exhibit molecular motions that contribute to proton conduction. Despite its anisotropic H‐bonded network, the salt exhibits isotropic anhydrous superprotonic conductivity exceeding 10<jats:sup>−3</jats:sup> S cm<jats:sup>−1</jats:sup> at ≈351 K, which is the first example for organic molecular crystal. Variable‐temperature X‐ray structural analysis and solid‐state <jats:sup>2</jats:sup>H NMR measurements revealed significant 3D molecular motion of imidazolium cations, which accelerate proton conduction via the 3D H‐bonded phosphate network.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition
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Angewandte Chemie International Edition 61 (49), e202212872-, 2022-11-10
Wiley