Electrochemical Synthesis of Hetero[7]helicenes Containing Pyrrole and Furan Rings <i>via</i> an Oxidative Heterocoupling and Dehydrative Cyclization Sequence
-
- Mohamed S. H. Salem
- SANKEN Osaka University Ibaraki-shi Osaka 567-0047 Japan
-
- Md. Imrul Khalid
- SANKEN Osaka University Ibaraki-shi Osaka 567-0047 Japan
-
- Makoto Sako
- Graduate School of Pharmaceutical Sciences Osaka University Suita-shi Osaka 565-0871 Japan
-
- Keigo Higashida
- SANKEN Osaka University Ibaraki-shi Osaka 567-0047 Japan
-
- Charlie Lacroix
- Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), CNRS-UMR 8182 Laboratoire de Catalyse Moléculaire Université Paris-Saclay 91405 Orsay Cedex France
-
- Masaru Kondo
- Department of Materials Science and Engineering Graduate School of Science and Engineering Ibaraki University Hitachi-shi Ibaraki 316-8511 Japan
-
- Ryo Takishima
- Department of Applied Chemistry Graduate School of Engineering Osaka University Suita-shi Osaka 565-0871 Japan
-
- Taisei Taniguchi
- Department of Applied Chemistry Graduate School of Engineering Osaka University Suita-shi Osaka 565-0871 Japan
-
- Masahiro Miura
- Innovative Catalysis Science Division Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI) Osaka University Suita-shi Osaka 565-0871 Japan
-
- Giang Vo‐Thanh
- Institut de Chimie Moléculaire et des Matériaux d'Orsay (ICMMO), CNRS-UMR 8182 Laboratoire de Catalyse Moléculaire Université Paris-Saclay 91405 Orsay Cedex France
-
- Hiroaki Sasai
- SANKEN Osaka University Ibaraki-shi Osaka 567-0047 Japan
-
- Shinobu Takizawa
- SANKEN Osaka University Ibaraki-shi Osaka 567-0047 Japan
抄録
<jats:title>Abstract</jats:title><jats:p>The electrochemical synthesis of hetero[7]helicenes including pyrrole and furan rings has been established. A single electrochemical operation led to an oxidative heterocoupling and dehydrative cyclization sequence to afford oxaza[7]helicenes in 50–86% yields with 45–77% Faradic efficiencies. Their derivatization and chiroptical properties were also investigated.</jats:p><jats:p><jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/png" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/adsc202201262-toc-0001-m.png"><jats:alt-text>magnified image</jats:alt-text></jats:graphic></jats:boxed-text> </jats:p>
収録刊行物
-
- Advanced Synthesis & Catalysis
-
Advanced Synthesis & Catalysis 365 (3), 373-380, 2023-01-24
Wiley
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1360016870538630656
-
- ISSN
- 16154169
- 16154150
-
- データソース種別
-
- Crossref
- KAKEN