Achievements of NEDO Durability Projects on SOFC Stacks in the Light of Physicochemical Mechanisms
-
- H. Yokokawa
- The University of Tokyo Institute of Industrial Science 4‐6‐1 Komaba, Meguro‐ku 153‐8505 Tokyo Japan
-
- M. Suzuki
- Osaka Gas. Co. Ltd. 6‐19‐9 Torishima, Konohaha‐ku 554‐0051 Osaka Japan
-
- M. Yoda
- Osaka Gas. Co. Ltd. 6‐19‐9 Torishima, Konohaha‐ku 554‐0051 Osaka Japan
-
- T. Suto
- Mitsubishi Hitachi Power Systems, Ltd. Fuel Cell Business Department 1‐1 Akunoura‐machi, Nagasaki 850‐8610 Nagasaki Japan
-
- K. Tomida
- Mitsubishi Hitachi Power Systems, Ltd. Fuel Cell Business Department 1‐1 Akunoura‐machi, Nagasaki 850‐8610 Nagasaki Japan
-
- K. Hiwatashi
- Mitsubishi Hitachi Power Systems, Ltd. Fuel Cell Business Department 1‐1 Akunoura‐machi, Nagasaki 850‐8610 Nagasaki Japan
-
- M. Shimazu
- TOTO Ltd. 2‐8‐1Honson, Chigasaki 253‐8577 Kanagawa Japan
-
- A. Kawakami
- TOTO Ltd. 2‐8‐1Honson, Chigasaki 253‐8577 Kanagawa Japan
-
- H. Sumi
- NGK SPARK PLUG 2808 Oaza‐Iwasaki, Komaki 485‐8510 Aichi Japan
-
- M. Ohmori
- NGK INSULATORS, Ltd. 2‐56 Suda‐cho, Mizuho, Nagoya 467‐8530 Aichi Japan
-
- T. Ryu
- NGK INSULATORS, Ltd. 2‐56 Suda‐cho, Mizuho, Nagoya 467‐8530 Aichi Japan
-
- N. Mori
- Murata Manufacturing Co., Ltd. 1‐10‐1, Higashikotari, Nagaokakyo‐shi 617‐8555 Kyoto Japan
-
- M. Iha
- Murata Manufacturing Co., Ltd. 1‐10‐1, Higashikotari, Nagaokakyo‐shi 617‐8555 Kyoto Japan
-
- S. Yatsuzuka
- DENSO CORPORATION 1‐1 Showa‐cho, Kariya 448‐8661 Aichi Japan
-
- K. Yamaji
- The National Institute of Advanced Industrial Science and Technology (AIST) Department of Energy and Environment 305‐8565 Ibaraki Japan
-
- H. Kishimoto
- The National Institute of Advanced Industrial Science and Technology (AIST) Department of Energy and Environment 305‐8565 Ibaraki Japan
-
- K. Develos‐Bagarinao
- The National Institute of Advanced Industrial Science and Technology (AIST) Department of Energy and Environment 305‐8565 Ibaraki Japan
-
- T. Shimonosono
- The National Institute of Advanced Industrial Science and Technology (AIST) Department of Energy and Environment 305‐8565 Ibaraki Japan
-
- K. Sasaki
- Kyushu University Next‐Generation Fuel Cell Research Center (NEXT‐FC); International Research Center for Hydrogen Energy 744 Motooka Nishi‐ku 819‐0325 Fukuoka Japan
-
- S. Taniguchi
- Kyushu University Next‐Generation Fuel Cell Research Center (NEXT‐FC); International Research Center for Hydrogen Energy 744 Motooka Nishi‐ku 819‐0325 Fukuoka Japan
-
- T. Kawada
- Tohoku University Graduate School of Environmental Studies 980‐8579 Sendai Japan
-
- M. Muramatsu
- Tohoku University Graduate School of Environmental Studies 980‐8579 Sendai Japan
-
- K. Terada
- Tohoku University Graduate School of Environmental Studies 980‐8579 Sendai Japan
-
- K. Eguchi
- Kyoto University Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering Nishikyo‐ku 615‐8510 Kyoto Japan
-
- T. Matsui
- Kyoto University Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering Nishikyo‐ku 615‐8510 Kyoto Japan
-
- H. Iwai
- Kyoto University Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering Nishikyo‐ku 615‐8510 Kyoto Japan
-
- M. Kishimoto
- Kyoto University Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering Nishikyo‐ku 615‐8510 Kyoto Japan
-
- N. Shikazono
- The University of Tokyo Institute of Industrial Science 4‐6‐1 Komaba, Meguro‐ku 153‐8505 Tokyo Japan
-
- Y. Mugikura
- Central Research Institute of Electric Power Industry (CRIEPI) 2‐6‐1 Nagasaka, Yokosuka 240‐0196 Kanagawa Japan
-
- T. Yamamoto
- Central Research Institute of Electric Power Industry (CRIEPI) 2‐6‐1 Nagasaka, Yokosuka 240‐0196 Kanagawa Japan
-
- M. Yoshikawa
- Central Research Institute of Electric Power Industry (CRIEPI) 2‐6‐1 Nagasaka, Yokosuka 240‐0196 Kanagawa Japan
-
- K. Yasumoto
- Central Research Institute of Electric Power Industry (CRIEPI) 2‐6‐1 Nagasaka, Yokosuka 240‐0196 Kanagawa Japan
-
- K. Asano
- Central Research Institute of Electric Power Industry (CRIEPI) 2‐6‐1 Nagasaka, Yokosuka 240‐0196 Kanagawa Japan
-
- Y. Matsuzaki
- Tokyo Gas Co., Ltd. Energy System Research Institute 3‐13‐1 Minami‐Senju, Arakawa‐ku 116‐0003 Tokyo Japan
-
- K. Sato
- Tokyo Gas Co., Ltd. Energy System Research Institute 3‐13‐1 Minami‐Senju, Arakawa‐ku 116‐0003 Tokyo Japan
-
- T. Somekawa
- Tokyo Gas Co., Ltd. Energy System Research Institute 3‐13‐1 Minami‐Senju, Arakawa‐ku 116‐0003 Tokyo Japan
説明
<jats:title>Abstract</jats:title><jats:p>Achievements of NEDO durability projects on SOFC mode are summarized with a focus on the physicochemical mechanisms characterized by diffusion properties of cell components and chemical reactions of cell components with gaseous impurities. Ni sintering and depletion including impurity (P, B, S) effects have been examined in terms of the surface/interface energies of Ni/oxide cermet anodes. The conductivity degradation due to the transformation of the cubic YSZ electrolyte was found to be characterized in terms of two time constants for the reductive and the oxidative regions to be determined by the Y‐diffusivity and its enhancement on NiO internal reduction in YSZ, while observed gaps in conductivity degradation behavior between stacks and button cells were ascribed to differences in those physicochemical properties involved, namely cation diffusion and kinetics associated with NiO internal reduction. The cathode performance degradation due to sulfur poisoning exhibits a variety of dependences on the microstructure (dense or porous) of doped‐ceria interlayers, the thickness of YSZ electrolyte and the humidity in the anode atmosphere, suggesting effects of protons in the cathode vicinity and the SrO activity changes during fabrication the LSCF/GDC/YSZ multilayers. Some defect chemical considerations were made on how such defects are affected by fabrication processes.</jats:p>
収録刊行物
-
- Fuel Cells
-
Fuel Cells 19 (4), 311-339, 2019-06-03
Wiley
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1360016979573625088
-
- ISSN
- 16156854
- 16156846
-
- データソース種別
-
- Crossref
- OpenAIRE
