Effects of self-hydrogen bonding among formamide molecules on the UCST-type liquid–liquid phase separation of binary solutions with imidazolium-based ionic liquid, [C<sub><i>n</i></sub>mim][TFSI], studied by NMR, IR, MD simulations, and SANS
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- Masahiro Kawano
- Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan
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- Atsuya Tashiro
- Department of Chemistry and Applied Chemistry, Graduate School of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan
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- Yuki Imamura
- Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan
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- Moeno Yamada
- Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan
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- Koichiro Sadakane
- Faculty of Life and Medical Sciences, Doshisha University, 1-3 Tatara Miyakodani, Kyotanabe, Kyoto 610-0394, Japan
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- Hiroki Iwase
- Comprehensive Research Organization for Science and Society (CROSS), 162-1 Shirakata, Tokai, Ibaraki 319-1106, Japan
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- Masaru Matsugami
- Faculty of Liberal Arts, National Institute of Technology (KOSEN), Kumamoto College, 2659-2 Suya, Koshi, Kumamoto 861-1102, Japan
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- Bogdan A. Marekha
- Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, 29 Jahnstr., 69230 Heidelberg, Germany
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- Abdenacer Idrissi
- University of Lille, CNRS, UMR 8516 – LASIRe - Laboratoire Avancé de Spectroscopie pour les Interactions la Réactivité et l’environnement, F-5900 Lille, France
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- Toshiyuki Takamuku
- Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi, Saga 840-8502, Japan
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説明
<jats:p>The UCST of phase separation for imidazolium-based ionic liquids [C<jats:sub><jats:italic>n</jats:italic></jats:sub>mim][TFSI] and formamide (FA) binary solutions increases with elongation of the alkyl chain length<jats:italic>n</jats:italic>. This is opposite to previous 1,4-dioxane solutions.</jats:p>
収録刊行物
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- Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics 24 (22), 13698-13712, 2022
Royal Society of Chemistry (RSC)
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詳細情報 詳細情報について
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- CRID
- 1360017282224119680
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- ISSN
- 14639084
- 14639076
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- 資料種別
- journal article
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- データソース種別
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