Intramolecular Propargylic Ene Reaction of Benzyne En Route to Highly Functionalized Allenes and Allenamides
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説明
<jats:title>Abstract</jats:title><jats:p>A variety of highly functionalized allenes and allenamides are prepared by intramolecular propargylic ene reactions of benzynes. Specific benzyne precursors having a chlorodiisopropylsilyl group serve as platforms to link with various propargyl alcohols via a Si–O bond, thereby expanding the scope of this reaction. Also demonstrated is a complete transmission of point to axial chirality to give a chiral, non-racemic allenamide. </jats:p>
収録刊行物
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- Synthesis
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Synthesis 54 (22), 4979-4988, 2022-04-14
Georg Thieme Verlag KG
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詳細情報 詳細情報について
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- CRID
- 1360017282463046272
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- ISSN
- 1437210X
- 00397881
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- 資料種別
- journal article
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- データソース種別
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- Crossref
- KAKEN