Intramolecular Propargylic Ene Reaction of Benzyne En Route to Highly Functionalized Allenes and Allenamides

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<jats:title>Abstract</jats:title><jats:p>A variety of highly functionalized allenes and allenamides are prepared by intramolecular propargylic ene reactions of benzynes. Specific benzyne precursors having a chlorodiisopropylsilyl group serve as platforms to link with various propargyl alcohols via a Si–O bond, thereby expanding the scope of this reaction. Also demonstrated is a complete transmission of point to axial chirality to give a chiral, non-racemic allenamide. </jats:p>

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  • Synthesis

    Synthesis 54 (22), 4979-4988, 2022-04-14

    Georg Thieme Verlag KG

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