Axial zero-field splitting in mononuclear Co(<scp>ii</scp>) 2-N substituted N-confused porphyrin: Co(2-NC<sub>3</sub>H<sub>5</sub>-21-Y-CH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>-NCTPP)Cl (Y = o, m, p) and Co(2-NC<sub>3</sub>H<sub>5</sub>-21-CH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>-NCTPP)Cl

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<p>Four inner <italic>C</italic>-benzyl and <italic>C</italic>-xylyl-substituted cobalt(<sc>ii</sc>) complexes of a 2-<italic>N</italic>-substituted N-confused porphyrin were synthesized and the <italic>D</italic>-parameter is related to the structural parameters of the cobalt(<sc>ii</sc>) complexes.</p>

Journal

  • Dalton Transactions

    Dalton Transactions 45 (11), 4854-4862, 2016

    Royal Society of Chemistry (RSC)

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