Hierarchical Metal‐Organic Network‐Forming Glasses toward Applications

  • Yong‐Sheng Wei
    Institute for Integrated Cell‐Material Sciences Institute for Advanced Study Kyoto University Yoshida‐Honmachi, Sakyo‐ku Kyoto 606–8501 Japan
  • Christopher W. Ashling
    Institute for Integrated Cell‐Material Sciences Institute for Advanced Study Kyoto University Yoshida‐Honmachi, Sakyo‐ku Kyoto 606–8501 Japan
  • Teerat Watcharatpong
    Department of Materials Science and Engineering School of Molecular Science and Engineering Vidyasirimedhi Institute of Science and Technology (VISTEC) Rayong 21210 Thailand
  • Zeyu Fan
    Department of Synthetic Chemistry and Biological Chemistry Graduate School of Engineering Kyoto University Katsura, Nishikyo‐ku Kyoto 615–8510 Japan
  • Satoshi Horike
    Institute for Integrated Cell‐Material Sciences Institute for Advanced Study Kyoto University Yoshida‐Honmachi, Sakyo‐ku Kyoto 606–8501 Japan

書誌事項

公開日
2023-11-20
資源種別
journal article
権利情報
  • http://creativecommons.org/licenses/by-nc/4.0/
DOI
  • 10.1002/adfm.202307226
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Glassy states of network‐forming coordination polymers (CPs) and metal‐organic frameworks (MOFs) represent a novel category of amorphous materials. Recent years have seen substantial progress in expanding the compound library and advancing the structural design of CP/MOF glasses. This review examines the current status and future potential of multi‐scale hierarchical CP/MOF glass materials, covering synthesis, shape adaptability, and synergistic materials. Extensive experimental and theoretical investigations of structure‐property relationships have shed light on their diverse utility, spanning areas such as permanent porosity and gas permeability, ionic and electronic conductivity, optics, catalysis, and battery technology. Additionally, the inherent properties of these glasses, coupled with their phase transformation capability, enable a range of morphological architectures. Current challenges are also addressed and offer insights into future research, with the goal of bringing CP/MOF glasses to the industry.</jats:p>

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