Intermolecular <i>exo</i> -selective Diels–Alder reaction catalysed by dual-functional Brønsted acid: conformational restriction of transition states by hydrogen bonds as the key interaction

DOI Web Site 被引用文献1件 参考文献86件 オープンアクセス
  • Taishi Nakanishi
    Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, Miyagi 980-8578, Japan
  • Masahiro Terada
    Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai, Miyagi 980-8578, Japan

書誌事項

公開日
2023
資源種別
journal article
権利情報
  • http://creativecommons.org/licenses/by-nc/3.0/
DOI
  • 10.1039/d3ra07688a
公開者
Royal Society of Chemistry (RSC)

説明

<jats:p> An <jats:italic>exo</jats:italic> -selective Diels–Alder reaction was predicted by a computational approach and was experimentally confirmed by the combined use of a dual-functional acid catalyst, such as phosphoric acid, and the conformationally restricted dienylcarbamate. </jats:p>

収録刊行物

  • RSC Advances

    RSC Advances 13 (51), 36293-36300, 2023

    Royal Society of Chemistry (RSC)

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