Photoswitchable Chiral Organocatalysts: Photocontrol of Enantioselective Reactions
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- Masaru Kondo
- Department of Materials Science and Engineering Graduate School of Science and Engineering Ibaraki University Hitachi-shi Ibaraki 316-8511 Japan
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- Kento Nakamura
- SANKEN Osaka University Mihogaoka Ibaraki-shi Osaka 567-0047 Japan
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- Chandu G. Krishnan
- SANKEN Osaka University Mihogaoka Ibaraki-shi Osaka 567-0047 Japan
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- Hiroaki Sasai
- SANKEN Osaka University Mihogaoka Ibaraki-shi Osaka 567-0047 Japan
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- Shinobu Takizawa
- SANKEN Osaka University Mihogaoka Ibaraki-shi Osaka 567-0047 Japan
書誌事項
- 公開日
- 2023-04-03
- 資源種別
- journal article
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/tcr.202300040
- 公開者
- Wiley
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説明
<jats:title>Abstract</jats:title><jats:p>This study presents recent advances in photoswitchable chiral organocatalysts and their applications in the photomodulation of enantioselective reactions. Under irradiation with an appropriate wavelength of light, the <jats:italic>E</jats:italic>/<jats:italic>Z</jats:italic>‐photoisomerization of the photoresponsive units on the catalysts leads to the control of the catalytic activity and/or selectivity of the enantioselective reactions. Additionally, this study elucidates the design, synthesis, and catalytic application of the fabricated azobenzene BINOL‐based photoswitchable chiral phase‐transfer catalysts. This account will provide insights into the appropriate design of a photoswitchable chiral organocatalyst that can achieve both good enantioselectivity and photocontrol.</jats:p>
収録刊行物
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- The Chemical Record
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The Chemical Record 23 (7), e202300040-, 2023-04-03
Wiley
