Side-Chain Type Ferrocene Macrocycles

DOI Web Site 参考文献79件
  • Bin Lan
    Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry
  • Jindong Xu
    Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry
  • Lingyun Zhu
    Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry
  • Xinyu Chen
    Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry
  • Hideya Kono
    Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University
  • Peihan Wang
    School of Materials Science and Engineering, National Institute for Advanced Materials
  • Xin Zuo
    Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry
  • Jianfeng Yan
    Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry
  • Akiko Yagi
    Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University
  • Yongshen Zheng
    School of Materials Science and Engineering, National Institute for Advanced Materials
  • Songhua Chen
    College of Chemistry and Material Science
  • Yaofeng Yuan
    Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry
  • Kenichiro Itami
    Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University
  • Yuanming Li
    Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry

書誌事項

公開日
2024-03-13
資源種別
journal article
権利情報
  • https://creativecommons.org/licenses/by/4.0/
DOI
  • 10.1021/prechem.3c00121
公開者
American Chemical Society (ACS)

この論文をさがす

説明

[Image: see text] A class of side-chain type ferrocene macrocycles with a radially conjugated system is introduced in this study. The stereo configurations of these ferrocene rings were determined through single-crystal X-ray diffraction analysis. Notably, in the solid state, the ferrocene rings exhibit a distinctive herringbone stacking pattern imposed by a ferrocene-to-ring host–guest interaction. Through UV–vis absorption spectroscopy, electrochemical measurements, and theoretical calculations, valuable insights into the electronic properties of these rings were obtained. In addition, the single crystal of macrocycle A(2)B demonstrates a second-order nonlinear optical response. As a class of organometallic nanorings, this work holds great potential for further exploration in the fields of organometallic chemistry, molecular electronics, and host–guest chemistry.

収録刊行物

  • Precision Chemistry

    Precision Chemistry 2 (4), 143-150, 2024-03-13

    American Chemical Society (ACS)

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