Platinum as a Reference Electrode in Electrochemical Measurements

  • By Kasem K. Kasem
    Department of Natural, Information, and Mathematical Science, Indiana University KokomoKokomo, IN, 46904-9003U.S.A.
  • Stephanie Jones
    Department of Natural, Information, and Mathematical Science, Indiana University KokomoKokomo, IN, 46904-9003U.S.A.

書誌事項

公開日
2008-04-01
DOI
  • 10.1595/147106708x297855
公開者
Johnson Matthey Plc

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説明

<jats:p> <jats:italic>The usefulness of platinum as an electrochemical reference electrode was investigated. Well known redox systems with one-electron single or multiple redox waves, and two-electron multiple redox waves were used as test regimes. The effects on electrode performance of variables such as the solvent, the physical state of the electrolyte and its temperature were investigated. Cyclic voltammetry (CV) was used to derive kinetic parameters for comparison with corresponding measurements on traditional reference electrodes. The results indicate that Pt can be used as a reference electrode under specific conditions in which traditional reference electrodes cannot be used.</jats:italic> </jats:p>

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