Development of a Palladium on Boron Nitride Catalyst and its Application to the Semihydrogenation of Alkynes

Abstract

<jats:title>Abstract</jats:title><jats:p>The simple preparative method for a novel palladium supported on boron nitride catalyst (Pd/BN) was accomplished. Pd/BN is widely applicable for the semihydrogenation of mono‐ as well as disubstituted alkynes to furnish the corresponding alkenes in the presence of diethylenetriamine (DETA), which exhibits both an unprecedented acceleration effect toward the semihydrogenation and a suppression effect with regard to the overhydrogenation to alkanes.</jats:p>

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