Buchwald–Hartwig Amination of Nitroarenes

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  • Fumiyoshi Inoue
    Department of Material Chemistry Graduate School of Engineering Kyoto University Katsura, Nishikyo-ku Kyoto 615-8510 Japan
  • Myuto Kashihara
    Department of Material Chemistry Graduate School of Engineering Kyoto University Katsura, Nishikyo-ku Kyoto 615-8510 Japan
  • M. Ramu Yadav
    Department of Material Chemistry Graduate School of Engineering Kyoto University Katsura, Nishikyo-ku Kyoto 615-8510 Japan
  • Yoshiaki Nakao
    Department of Material Chemistry Graduate School of Engineering Kyoto University Katsura, Nishikyo-ku Kyoto 615-8510 Japan

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<jats:title>Abstract</jats:title><jats:p>The Buchwald–Hartwig amination of nitroarenes was achieved for the first time by using palladium catalysts bearing dialkyl(biaryl)phosphine ligands. These cross‐coupling reactions of nitroarenes with diarylamines, arylamines, and alkylamines afforded the corresponding substituted arylamines. A catalytic cycle involving the oxidative addition of the Ar−NO<jats:sub>2</jats:sub> bond to palladium(0) followed by nitrite/amine exchange is proposed based on a stoichiometric reaction.</jats:p>

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