The Quenching of Hg(63<i>P</i>1) Atoms by Molecular Hydrogen as Investigated by ESR Spectroscopy
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- James B Farmer
- Department of Chemistry, University of British Columbia
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- Kazuo Shimokoshi
- Department of Chemistry, University of British Columbia
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説明
<jats:title>Abstract</jats:title> <jats:p>The gas phase electron spin resonance technique has been applied to study the quenching efficiency of Hg(63P1) mercury atoms by molecular hydrogen. The concentration of hydrogen atoms produced by the mercury photosensitized decomposition of molecular hydrogen in a flow apparatus was followed as a function of the partial pressure of hydrogen with argon, neon, and hydrogen as carrier gases. The kinetic equations derived from the reaction mechanism proposed was shown to be in agreement with the experimental observations. The total quenching rate kH was evaluated from the experimental results.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 45 (8), 2269-2273, 1972-08-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360283694076348672
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- NII論文ID
- 130001974993
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- ISSN
- 13480634
- 00092673
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