Pressure-Volume-Temperature Relations of Supercooled Liquid and Glass of Triphenylchloromethane/<i>o</i>-Terphenyl Mixture
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- Motosuke Naoki
- Department of Textiles and Polymers, Faculty of Technology, Gunma University
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- Manabu Matsushita
- Department of Textiles and Polymers, Faculty of Technology, Gunma University
Abstract
<jats:title>Abstract</jats:title> <jats:p>Volumetric data on the supercooled liquid state and on the glassy state are reported for a binary mixture of triphenylchloromethane and o-terphenyl. In the supercooled liquid state, the thermal expansivity, the isothermal compressibility, and their temperature dependences of the mixture are much samller than those of simple molecular liquids and are almost the same order of magnitude as those of polymer liquids. The glass of the mixture also closely resembles polymer glasses in the apparent thermodynamic properties. Some representative lattice-like liquid theories are applied to the pressure-volume-temperature relations of the supercooled liquid sample, with the aid of the principle of corresponding states.</jats:p>
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 56 (12), 3549-3555, 1983-12-01
Oxford University Press (OUP)
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Keywords
Details 詳細情報について
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- CRID
- 1360283694078782848
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- NII Article ID
- 130001985546
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- ISSN
- 13480634
- 00092673
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- Data Source
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- Crossref
- CiNii Articles