Micellar Effects upon Spontaneous and Alkaline Hydrolysis of <i>t</i>-Butyl Phenyl Carbonate
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- Hamad A Al-Lohedan
- Department of Chemistry, College of Science, King Saud University
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- Mohammed I Al-Hassan
- Department of Chemistry, College of Science, King Saud University
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説明
<jats:title>Abstract</jats:title> <jats:p>Cationic micelles of hexadecyltrimethylammonium ion HTAX (X=Cl− and OH−) catalyzes the reactions of t-butyl phenyl carbonate with OH− and kΨ goes through maximum with increasing [HTACl] but it continues to increase with increasing [HTAOH]. Spontaneous hydrolysis of t-butyl phenyl carbonate is inhibited by both cationic and anionic micelles. The second-order rate constant in micelles is smaller than that in water.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 63 (10), 2997-3000, 1990-10-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360283694080125312
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- NII論文ID
- 130001979990
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- ISSN
- 13480634
- 00092673
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- データソース種別
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