Micellar Effects upon Spontaneous and Alkaline Hydrolysis of <i>t</i>-Butyl Phenyl Carbonate

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<jats:title>Abstract</jats:title> <jats:p>Cationic micelles of hexadecyltrimethylammonium ion HTAX (X=Cl− and OH−) catalyzes the reactions of t-butyl phenyl carbonate with OH− and kΨ goes through maximum with increasing [HTACl] but it continues to increase with increasing [HTAOH]. Spontaneous hydrolysis of t-butyl phenyl carbonate is inhibited by both cationic and anionic micelles. The second-order rate constant in micelles is smaller than that in water.</jats:p>

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