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- Takehiko Mori
- Institute for Molecular ScienceOkazaki 444
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- Hiroo Inokuchi
- Institute for Molecular ScienceOkazaki 444
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- Yohji Misaki
- Department of Molecular Engineering, Kyoto UniversityYoshida, Kyoto 606
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- Tokio Yamabe
- Department of Molecular Engineering, Kyoto UniversityYoshida, Kyoto 606
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- Hatsumi Mori
- International Superconductivity Technology CentrerMutsuno, Nagoya 456
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- Shoji Tanaka
- International Superconductivity Technology CentrerMutsuno, Nagoya 456
説明
<jats:title>Abstract</jats:title> <jats:p>Methylthio substituted bis-fused tetrathiafulvalene, TTM-TTP (2,5-bis[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-1,3,4,6-tetrathiaphentalene) makes three phases of iodine complexes: (TTM-TTP)I3, α-(TTM-TTP)2I3, and β-(TTM-TTP)2I3. The 1 : 1 complex exhibits high conductivity, 700 S cm−1 at room temperature, and is metallic down to about TMI = 160 K. This complex has uniform columns of the donor molecules. In the semiconducting α-(TTM-TTP)2I3, one quarter of the donors is incorporated in the anion sheet, and the sides of the other trimeric donors are blocked by the anion sheets. β-(TTM-TTP)2I3 shows metallic conductivity down to TMI = 20 K.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 67 (3), 661-667, 1994-03-01
Oxford University Press (OUP)
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360283694080819456
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- NII論文ID
- 130004148623
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- ISSN
- 13480634
- 00092673
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- データソース種別
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- Crossref
- CiNii Articles
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