59Co Nuclear Quadrupole Interaction in Crystalline <i>Δ</i>-Tris[<i>trans</i>-(1<i>R</i>,2<i>R</i>)-1,2-diaminocyclohexane]cobalt(III) Chloride Trihydrate
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- Takahiro Ueda
- Department of Chemistry, Graduate School of Science, Osaka UniversityToyonaka, Osaka 560
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- Nobuo Nakamura
- Department of Chemistry, Graduate School of Science, Osaka UniversityToyonaka, Osaka 560
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- Masayasu Iida
- Department of Chemistry, Faculty of Science, Nara Women’s UniversityNara 630
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<jats:title>Abstract</jats:title> <jats:p>The lineshape of 59Co NMR was measured on solid [Co(chxn)3]3+ (chxn = trans-(1R,2R)-1,2-diaminocyclohexane) at the Larmor frequencies of 47 and 96 MHz. The 59Co nuclear quadrupole coupling constant and the asymmetry parameter of the electric field gradient were determined to be 7.50 MHz and 0.75, respectively. These values correspond to a very small distortion of the complex cation in the crystal.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 72 (9), 2029-2031, 1999-09-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360283694081299072
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- NII論文ID
- 130004150466
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- ISSN
- 13480634
- 00092673
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