Oxidative Dehydrogenation of Propane on Magnesium Vanadates in the Presence of Tetrachloromethane
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- Shigeru Sugiyama
- Department of Chemical Science and Technology, Faculty of Engineering, The University of TokushimaMinamijosanjima, Tokushima 770-8506
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- Yutaka Iizuka
- Department of Chemical Science and Technology, Faculty of Engineering, The University of TokushimaMinamijosanjima, Tokushima 770-8506
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- Yukinori Konishi
- Department of Chemical Science and Technology, Faculty of Engineering, The University of TokushimaMinamijosanjima, Tokushima 770-8506
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- Hiromu Hayashi
- Department of Chemical Science and Technology, Faculty of Engineering, The University of TokushimaMinamijosanjima, Tokushima 770-8506
説明
<jats:title>Abstract</jats:title> <jats:p>The oxidative dehydrogenation of propane to propene on active catalysts such as magnesium vanadates (MgV2O6, Mg2V2O7, and Mg3V2O8) has been investigated in the presence and absence of tetrachloromethane (TCM) at 723 K. The introduction of a small amount of TCM into the feedstream did not influence the selectivity to propene while the conversion of propane was improved on those catalysts. The conversion was enhanced by approximately twice on Mg2V2O7 upon addition of TCM. It has been shown that the effects of TCM on lattice oxygen in those catalysts mainly control the enhancement. The formation of an excess amount of the chlorinated species on the surface of the catalysts resulted in a decrease of the conversion.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 75 (1), 181-186, 2002-01-01
Oxford University Press (OUP)
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360283694081539840
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- NII論文ID
- 130004151013
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- ISSN
- 13480634
- 00092673
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