Preparation and Structure of <i>syn</i>- and <i>anti</i>-Bis(μ-thioacetato-κ2S)bis[bis(dithioacetato-κS:κS′)iridium(III)]

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<jats:title>Abstract</jats:title> <jats:p>Iridium(III) dinuclear complexes with thioacetato bridges and dithioacetato chelates were prepared by the reaction of H2IrCl6·6H2O with a mixture of Li2CO3, MeCOSH, MeCO2H, and (MeCO)2O under O2. X-ray structures of two geometrical isomers for [{Ir(S2CMe)2}2(μ-SOCMe)2] were determined.</jats:p>

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