Conversion of 2-Aminoethanethiolate (aet) to 2-Benzoylaminoethanethiolate (L) in a <i>S</i>-Bridged Diruthenium(II) Complex Composed of Two <i>cis</i>-[Ru(bpy)2] Units. Crystal Structures of ΔΔ/ΛΛ-[{Ru(bpy)2}2(μ-Haet)2]4+ and ΔΔ/ΛΛ-[{Ru(bpy)2}2(μ-L)2]2+

DOI PDF 研究データあり 被引用文献1件 参考文献15件
  • Noriyuki Matsuura
    Department of Chemistry, Graduate School of Science, Osaka University
  • Tatsuya Kawamoto
    Department of Chemistry, Graduate School of Science, Osaka University
  • Takumi Konno
    Department of Chemistry, Graduate School of Science, Osaka University

この論文をさがす

説明

<jats:title>Abstract</jats:title> <jats:p>A diruthenium(II) complex, ΔΔ/ΛΛ-[{Ru(bpy)2}2(μ-L)2]2+ (ΔΔ/ΛΛ-[2]2+), in which two cis-[Ru(bpy)2]2+ units are bridged by two S atoms from two 2-benzoylaminoethanethiolate (L) ligands, was synthesized by the reaction of ΔΔ/ΛΛ-[{Ru(bpy)2}2(μ-Haet)2]4+ (aet = 2-aminoethanethiolate; ΔΔ/ΛΛ-[1]4+) with benzoyl chloride in the presence of a base. The molecular structure and electrochemical properties of ΔΔ/ΛΛ-[2]2+ were discussed in comparison with those of ΔΔ/ΛΛ-[1]4+.</jats:p>

収録刊行物

被引用文献 (1)*注記

もっと見る

参考文献 (15)*注記

もっと見る

関連研究データ

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ