Cu-catalyzed Reductive Coupling of Perfluoroarenes with 1,3-Dienes

DOI Web Site 4 Citations 45 References
  • Takanori Iwasaki
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871
  • Kanako Okamoto
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871
  • Hitoshi Kuniyasu
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871
  • Nobuaki Kambe
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871

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Description

Copper complexes, generated by the treatment of CuCl2 with EtMgCl, catalyze a reductive coupling reaction of perfluoroarenes with 1,3-dienes via C–F bond cleavage, in which the internal carbon of 1,3-dienes preferably reacts with perfluoroarenes giving rise to branched allylated perfluoroarenes as a major coupling product.

Journal

  • Chemistry Letters

    Chemistry Letters 46 (10), 1504-1507, 2017-10-05

    Oxford University Press (OUP)

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