Synthesis and Crystal Structure of Polymeric Oxovanadium(V) Complexes with Tetradentate Schiff Base Ligands

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  • Masanobu Tsuchimoto
    Department of Chemistry, Faculty of Science and Technology, Keio University
  • Eriko Yasuda
    Department of Chemistry, Faculty of Science and Technology, Keio University
  • Shigeru Ohba
    Department of Chemistry, Faculty of Science and Technology, Keio University

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<jats:title>Abstract</jats:title> <jats:p>New polymeric oxovanadium(V) complexes with tetradentate Schiff base ligands, [VO(Xsalen)]SbF6 (H2Xsalen: N,N′-di-Xsalicylidene-1, 2-ethanediamine; X=5-MeO (methoxy) and H ) were prepared from monomeric [VO(Xsalen)(H2O)]NO3·H2O by changing the counter anion. X-Ray crystal structure analysis of [VO(5-MeOsalen)]SbF6 showed that the complex has ···VV=O···VV=O··· chains in the crystals.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 29 (5), 562-563, 2000-05-01

    Oxford University Press (OUP)

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