A Novel Organic Conductor with Two-Dimensional Molecular Array by the “Edge-to-Edge” Donor Interaction

  • Kazuyuki Takahashi
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Takashi Nakayashiki
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Masateru Taniguchi
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Yohji Misaki
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Kazuyoshi Tanaka
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University

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Description

<jats:title>Abstract</jats:title> <jats:p>The title donor, where SM-PDT is 2-[4,5-bis(selenomethyl)-1,3-dithiol-2-ylidene]-5-(pyran-4-ylidene)-1,3,4,6-tetrathiapentalene, formed semiconducting 1:1 salts with various anions. The crystal structure analysis of (SM-PDT)PF6(PhCl)x has revealed that an edge-to-edge chalcogen interaction gave two-dimensional sheet-like structure.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 30 (2), 162-163, 2001-02-01

    Oxford University Press (OUP)

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