New Autocatalytic Mechanism for Metal Electrodeposition Leading to Oscillations and Fern-Leaf-Shaped Deposits

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  • Shuji Nakanishi
    Department of Chemistry, Graduate School of Engineering Science, Osaka UniversityToyonaka, Osaka
  • Kazuhiro Fukami
    Department of Chemistry, Graduate School of Engineering Science, Osaka UniversityToyonaka, Osaka
  • Sho-ichiro Sakai
    Department of Chemistry, Graduate School of Engineering Science, Osaka UniversityToyonaka, Osaka
  • Yoshihiro Nakato
    Department of Chemistry, Graduate School of Engineering Science, Osaka UniversityToyonaka, Osaka

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<jats:title>Abstract</jats:title> <jats:p>Zinc electrodeposition on a zinc electrode with a rough surface showed a potential oscillation, accompanied by fern-leaf-shaped deposits, contrary to the case of a zinc electrode with a smooth surface. A new autocatalytic mechanism based on a rough electrode surface is proposed to explain the phenomena systematically.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 31 (6), 636-637, 2002-06-01

    Oxford University Press (OUP)

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