Unusual Solvatochromism Based on Intramolecular Hydrophobic Interaction in Water-soluble Azobenzene Dendrimers

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  • Atsuya Momotake
    Research Facility Centre for Science and Technology, University of Tsukuba
  • Tatsuo Arai
    Graduate School of Pure and Applied Sciences, University of Tsukuba

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<jats:title>Abstract</jats:title> <jats:p>Azobenzene dendrimer E-2, having water-soluble dendrons at the ortho-position in azobenzene, showed novel solvatochromism with changing the solvent ratio of water/EtOH which is based on the intramolecular hydrophobic interaction due to poly-aryl(ether) dendrons. The thermodynamic parameters for Z-to-E thermal isomerization of 2 also greatly depended on the water/EtOH ratio.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 34 (3), 310-311, 2005-01-29

    Oxford University Press (OUP)

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