Switching Reaction Pathways of Benzo[<i>b</i>]thiophen-3-yllithium and Benzo[<i>b</i>]furan-3-yllithium Based on High-resolution Residence-time and Temperature Control in a Flow Microreactor
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- Tatsuro Asai
- The Research Association of Micro Chemical Process Technology (MCPT) in Kyoto, Kyoto University
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- Atsushi Takata
- Yamada Chemical Co., Ltd
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- Yousuke Ushiogi
- Yamada Chemical Co., Ltd
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- Yoshiharu Iinuma
- Yamada Chemical Co., Ltd
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- Aiichiro Nagaki
- Department of Synthetic and Biological Chemistry, Graduate School of Engineering, Kyoto University
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- Jun-ichi Yoshida
- Department of Synthetic and Biological Chemistry, Graduate School of Engineering, Kyoto University
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<jats:title>Abstract</jats:title> <jats:p>Reaction-pathway control of benzo[b]thiophen-3-yllithium and benzo[b]furan-3-yllithium was accomplished in flow microreactor systems. We could switch between the reaction with an electrophile before ring-opening and that after ring-opening at will by choosing an appropriate residence-time and temperature.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 40 (4), 393-395, 2011-03-12
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360283694088251520
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- NII論文ID
- 10028170699
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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