Single-component Layered Molecular Conductor, [Au(ptdt)2]

  • Biao Zhou
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Hiroyuki Yajima
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Yuki Idobata
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Akiko Kobayashi
    Department of Chemistry, College of Humanities and Sciences, Nihon University
  • Tetsuya Kobayashi
    Department of Applied Physics, Nagoya University
  • Eiji Nishibori
    Department of Applied Physics, Nagoya University
  • Hiroshi Sawa
    Department of Applied Physics, Nagoya University
  • Hayao Kobayashi
    Department of Chemistry, College of Humanities and Sciences, Nihon University

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Description

<jats:title>Abstract</jats:title> <jats:p>A single-component layered molecular conductor, [Au(ptdt)2] (ptdt: propylenedithiotetrathiafulvalenedithiolate) was prepared. Unlike the single-component molecular metal, [Au(tmdt)2] (tmdt: trimethylenetetrathiafulvalenedithiolate) exhibiting three-dimensional compact molecular packing and antiferromagnetic transition at 110 K, the compressed pellet of the microcrystals of [Au(ptdt)2] exhibited fairly high conductivity and small temperature-independent paramagnetic susceptibility.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 41 (2), 154-156, 2012-01-28

    Oxford University Press (OUP)

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