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Sulfate‐Based Cathode Materials for Li‐ and Na‐Ion Batteries
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- Laura Lander
- Department of Chemical System Engineering The University of Tokyo, Bunkyo-ku Tokyo 113-8656 Japan
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- Jean‐Marie Tarascon
- Laboratoire de la Chimie Solide et Energie Collège de France 75231 Paris France.
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- Atsuo Yamada
- Department of Chemical System Engineering The University of Tokyo, Bunkyo-ku Tokyo 113-8656 Japan
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Description
<jats:title>Abstract</jats:title><jats:p>Electrochemical energy storage <jats:italic>via</jats:italic> Li‐ion batteries has changed modern life drastically and has enabled technologies such as portable electronic devices, electric vehicles and stationary grid storage. However, with the steadfast technological evolution and increasing energy demands, batteries need to be constantly improved to meet the needs of our society. Furthermore, increasing concerns are raised regarding sustainability, availability of raw materials and cost. Therefore, extensive research efforts have been focused on the development of new battery types leading to the emergence of the Na‐ion technology and the discovery of a myriad of new materials. In this context, polyanions became a prominent alternative to layered oxides. A large variety of polyanionic frameworks has been studied in the past years including phosphates, silicates and borates, but it was especially sulfates, which attracted a lot of attention due to their elevated operating voltages. The here presented article gives an overview of the exhaustive research on sulfate‐based cathode materials for Li‐ and Na‐ion batteries discussing recent findings and future perspectives.</jats:p>
Journal
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- The Chemical Record
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The Chemical Record 18 (10), 1394-1408, 2018-09-11
Wiley