Visualization of conduction pathways in lithium superionic conductors: Li2S-P2S5 glasses and Li7P3S11 glass–ceramic
説明
Abstract For (Li 2 S) x (P 2 S 5 ) 100– x glasses and Li 7 P 3 S 11 glass–ceramic, which are well-known lithium superionic conductors, the conduction pathways of lithium ions were predicted and visualized by combining reverse Monte Carlo (RMC) modeling and the bond valence sum (BVS) method using synchrotron X-ray and time-of-flight neutron diffraction data. The conduction pathways of the lithium ions could be classified into two types: lithium ‘stable’ and ‘metastable’ regions. In addition, it was found that a significant relationship exists between the topology of the conduction pathways of the lithium ions and the activation energy of the electrical conduction.
収録刊行物
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- Chemical Physics Letters
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Chemical Physics Letters 584 113-118, 2013-10
Elsevier BV
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詳細情報 詳細情報について
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- CRID
- 1360285707061303680
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- ISSN
- 00092614
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- 資料種別
- journal article
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- データソース種別
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- Crossref
- KAKEN
- OpenAIRE
