Nucleophilic Substitution Reaction at the Nitrogen of Arylsulfonamides with Phosphide Anion
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- Suguru Yoshida
- Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580, Japan
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- Kazunobu Igawa
- Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580, Japan
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- Katsuhiko Tomooka
- Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, Fukuoka 816-8580, Japan
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説明
A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.
収録刊行物
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 134 (47), 19358-19361, 2012-11-14
American Chemical Society (ACS)