Asymmetric Synthesis of (+)-Geranyllinaloisocyanide: Assignment of Absolute Stereochemistry

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  • Yoshiyasu Ichikawa
    Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan and Faculty of Integrated Arts and Sciences, University of Tokushima, Tokushima 770-8502, Japan
  • Yasunori Matsuda
    Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan and Faculty of Integrated Arts and Sciences, University of Tokushima, Tokushima 770-8502, Japan
  • Ken Okumura
    Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan and Faculty of Integrated Arts and Sciences, University of Tokushima, Tokushima 770-8502, Japan
  • Mitsuhiro Nakamura
    Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan and Faculty of Integrated Arts and Sciences, University of Tokushima, Tokushima 770-8502, Japan
  • Toshiya Masuda
    Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan and Faculty of Integrated Arts and Sciences, University of Tokushima, Tokushima 770-8502, Japan
  • Hiyoshizo Kotsuki
    Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan and Faculty of Integrated Arts and Sciences, University of Tokushima, Tokushima 770-8502, Japan
  • Keiji Nakano
    Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan and Faculty of Integrated Arts and Sciences, University of Tokushima, Tokushima 770-8502, Japan

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<jats:title>Abstract</jats:title><jats:p>Based on the asymmetric synthesis of (+)‐geranyllinaloisocyanide (V) and spectroscopic comparison, it is found that natural geranyllinaloisocyanide has (S) configuration.</jats:p>

Journal

  • Organic Letters

    Organic Letters 13 (10), 2520-2523, 2011-04-14

    American Chemical Society (ACS)

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