Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization

  • Ryo Tanaka
    Department of Applied Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-hiroshima, 739-8527 Japan
  • Yuushou Nakayama
    Department of Applied Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-hiroshima, 739-8527 Japan
  • Takeshi Shiono
    Department of Applied Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-hiroshima, 739-8527 Japan

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Description

Organic halides and alkylaluminum chlorides are known as representative additives of lanthanide catalyst systems for the polymerization of conjugated dienes, which enhance the activity and stereosp...

Journal

  • Organometallics

    Organometallics 39 (10), 1855-1860, 2020-04-21

    American Chemical Society (ACS)

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